Brine characteristics: Points to consider
An exploration model will be crucial for Lithium X to understand the complex basin characteristics governing brine deposit formation as well as their development. Such a model would include the identification of prospective aquifers as well as structural controls on ground water flow, recharge rates, path ways/conduits and analysis of impurities such as magnesium, iron and sulphur (as sulphate).
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Focus on brines: Brine deposits are the mainstay of global lithium production and are relatively easy to scale up through the addition of more wells and evaporation ponds. They are generally lower grade than hard rock deposits, but far larger in resource size (other than for a small number of clay-based lithium deposits being developed by Bacanora Minerals, Lithium Americas and European Metal Holdings).
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Aquifer assessment: A detailed understanding of the hydrogeological characteristics governing brine deposits is crucial to understanding the quantities that can be economically extracted and, by extension, the size of operation that can be built. The 2011 Rodinia Lithium PEA on Salar de Diablillos contemplated a 15,000tpa LCE operation. This was based on the then current understanding of well flow rates, porosity and the number of aquifers at that time. An operation of this size is comparable to the 17,400tpa LCE plant treating Olaroz brines currently operated by Orocobre (ASX:ORE, ownership: 66.5%).
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Structural controls: Associated with the hydrogeological characteristics of brine deposits are any structural controls that govern ground water flow. This is important to understand such factors as brine recharge rates and whether brines get diluted from large inflows of water.
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Geochemistry: The chemical makeup of brine deposits is assessed beyond the assaying for economic minerals such as the lithium, borates and potash minerals commonly found. The level of impurities such as magnesium, iron and sulphur (as sulphate) requires careful assessment across all areas of the brine field subject to development, with elevated levels having a negative impact on operating costs. Sal de Los Angeles has a significant database of such data, which will be incorporated into the project’s feasibility study. Clayton Valley does not yet have drill data for us to comment on this. Operating costs rise in tandem with contaminant levels.
As can be seen in the following exhibit, Sal de Los Angeles has very favourable levels of magnesium and sulphate relative to lithium. The key magnesium to lithium ratio for Sal de Los Angeles is 3.8, 64% below the simple average for the peer group. The level of sulphates expressed as the SO4/Li ratio in the following exhibit also shows the project to have a very favourable ratio, 52% below the mean and 39% and 53% below Orocobre and Lithium America’s, respectively. The latter is notable as these projects are located in the same region as the Sal de Los Angeles project.
Exhibit 5: Chemistry of South American brine deposits
Deposit |
Operator |
Location |
Deposit type |
Grade Li |
Grade K |
Ratio |
Ratio |
Ratio |
(mg/l) |
(mg/l) |
K/Li |
Mg/Li |
SO4/Li |
Sal de Los Angeles |
Lithium X |
Argentina |
Na2SO4-K2SO4-Li2SO4 |
501* |
6,206 |
N/A |
3.8 |
14.6 |
Sal de Vida |
Galaxy |
Argentina |
Na2SO4-K2SO4-Li2SO4 |
782 |
8,653 |
11.1 |
2.2 |
11.5 |
Salar de Hombre Muerto |
FMC Corp |
Argentina |
Na2SO4-K2SO4-Li2SO4 |
744 |
7,404 |
10.0 |
1.4 |
13.8 |
Salar de Atacama |
Abermarle (Rockwood)/SQM |
Chile |
Sulpo-Li2S04-LiCl-CaCl2 |
1,835 |
22,626 |
12.3 |
6.4 |
11.0 |
Salar de Olaroz |
Orocobre |
Argentina |
Na2SO4-K2SO4-LiSO4 |
774 |
6,227 |
8.0 |
2.6 |
24.1 |
Salar de Cauchari |
Lithium Americas/SQM |
Argentina |
Na2SO4-K2SO4-LiSO4 |
618 |
5,127 |
8.3 |
2.9 |
30.9 |
Salar de Maricunga |
Li3 |
Chile |
KCl-LiCl-CaCl2 |
1,036 |
8,869 |
8.6 |
8.0 |
1.1 |
Salar de Uyuni |
COMIBOL |
Bolivia |
Sulpo-Li2SO4 |
424 |
8,719 |
20.6 |
18.6 |
24.4 |
Salar de Rincon |
Rincon Lithium |
Argentina |
Sulpo-Li2SO4 |
397 |
7,513 |
18.9 |
8.6 |
30.8 |
West Taijinaier |
Citic |
China |
Sulpo-Li2SO4 |
256 |
8,444 |
33.0 |
61.5 |
137.9 |
Zhabuye Salt Lake |
Unknown |
China |
Li2CO3-Na2SO4 |
1,217 |
17,083 |
14.0 |
0.0 |
32.0 |
|
|
|
|
|
|
|
|
|
Arithmetic average |
|
|
|
808 |
9,716 |
12.0 |
10.5 |
30.2 |
Source: Company websites and Edison Investment Research. Note: *Mean indicated category grade only.
Exhibit 6: Chemistry of Nevada brine deposits
Deposit |
Operator |
Location |
Deposit type |
Grade Li |
Grade K |
Ratio |
Ratio |
Ratio |
(mg/l) |
(mg/l) |
K/Li |
Mg/Li |
SO4/Li |
Clayton Valley |
Pure Energy |
Nevada |
Na2SO4-K2SO4-Li2SO4 |
102 |
1 |
N/A |
2.0 |
23.0 |
Clayton Valley North |
Lithium X |
Nevada |
Na2SO4-K2SO4-Li2SO4 |
N/A |
N/A |
N/A |
N/A |
N/A |
Clayton Valley South |
Lithium X |
Nevada |
Na2SO4-K2SO4-Li2SO4 |
N/A |
N/A |
N/A |
N/A |
N/A |
Silver Peak |
Albemarle (Rockwood) |
Nevada |
Na2SO4-K2SO4-Li2SO4 |
245 |
5,655 |
23.1 |
1.4 |
30.9 |
|
|
|
|
|
|
|
|
|
Arithmetic average |
|
|
|
174 |
2,828 |
16.3 |
1.7 |
27 |
Source: Company websites and Edison Investment Research
Technical management bolstered by ex-Rockwood CEO
Newly appointed Lithium X COO Eduardo Morales, a past-CEO of Rockwood Latin America before its takeover, has considerable local expertise in the development of brines similar to Los Angeles. Specifically, his expertise involves the development of South America’s first producing lithium carbonate plant. His experience will be invaluable as the company looks to firm up its understanding of the technical aspects of the Sal de Los Angeles project. His responsibilities will include addressing the development characteristics particular to brine deposits, such as:
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Mining: Brine deposits by their very nature cannot be mined by conventional means (ie dig and blast, underground or via open pit). Instead brines require a ‘well field’ to be developed with brines flowing to surface via artesian pressure or, if required, artificially pumped. This naturally places them, including Sal de Los Angeles and Clayton Valley, at the lower end of the global cost-curve for lithium producers.
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Metallurgy: Critical to the production of high-purity lithium products for use in the manufacture of lithium-ion batteries and other high-end technology applications. Levels of impurities must be assessed at the resource definition stage with any impurities (ie magnesium, iron and sulphates) removed. For the benefit of the end user, removal of impurities and the production of large volumes of consistent quality lithium carbonate or lithium hydroxide require the running of a pilot processing plant, such as that currently operated under JV by SESA. See page 4.
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Product sales: Lithium has no openly traded market and the majority of lithium produced is sold via contract with the end user (eg Panasonic, BYD, LG, etc). As such a company’s proven ability to produce consistently high-purity lithium products (as discussed above) is critical to it agreeing supply contracts and guaranteeing revenues.
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Infrastructure – Argentina: The closest producing lithium mine to Sal de Los Angeles is Salar de Hombre Muerto, located 130km to the north. A transfer facility is operated by FMC Corp at nearby Pocitos to handle concentrated Hombre Muerto brines. This operation has access to the La Puna Natural Gas pipeline and also the General Belgrano railroad. The 2011 Rodinia PEA on Salar de Diablillos contemplated a pre-treatment plant on site to produce concentrated brine for further treatment elsewhere, as well as potash for immediate sale. The concentrated brine, or bittern, would then be shipped to a LCE/Borates process facility at Pocitos, potentially allowing for access to the existing La Puna Natural Gas Pipeline and General Belgrano Railroad.
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Infrastructure – Nevada: Clayton Valley North and South are located next to an existing mine, Silver Peak. With the state of Nevada already being the US’s dominant mining region (mostly gold), we would not expect any major obstacle to development from an infrastructure point of view.
Exhibit 7: Idealised schematic of brine extraction and processing
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Source: Lithium X corporate presentation. Note: LIX does not currently envisage reinjection of brines from the pond to the salar.
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